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  5. <title>UTas ePrints - Formation of the Denchai gem sapphires, northern Thailand: evidence from mineral chemistry and fluid/melt inclusion characteristics</title>
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  13. <meta content="Limtrakun, P." name="eprints.creators_name" />
  14. <meta content="Zaw, K." name="eprints.creators_name" />
  15. <meta content="Ryan, C.G." name="eprints.creators_name" />
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  25. <meta content="Formation of the Denchai gem sapphires, northern Thailand: evidence from mineral chemistry and fluid/melt inclusion characteristics" name="eprints.title" />
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  29. <meta content="sapphire, Fluid and melt inclusions, alkaline magmatism, basalt, Thailand." name="eprints.keywords" />
  30. <meta content="Definitive version is available online at http://www.minersoc.org/pages/e_journals/minmag.html" name="eprints.note" />
  31. <meta content="The Denchai gem sapphire deposits in Phrae Province, northern Thailand are closely associated with
  32. late Cenozoic alkaline basaltic rocks. The sapphires occur in alluvial placer deposits in palaeo-channels
  33. at shallow depths. Electron microprobe analysis of minor and trace element contents (Fe, Ti, Cr, Ga
  34. and V) of the sapphires indicate the following oxide abundances: Fe2O3 (0.32-1.98 wt.%), TiO2
  35. (0.01-0.23 wt.%), Cr2O3 (<0.01 wt.%), Ga2O3 (0.01-0.03 wt.%) and V2O5 (<0.03 wt.%). Optical
  36. studies of sapphires revealed three types of primary fluid/melt inclusions. CO2-rich inclusions (Type I)
  37. contain three phases (LH2O + LCO2 + V) with the vapour phase comprising <10-15 vol.%. The presence of CO2 was confirmed by microthermometry and laser Raman analysis. Polyphase inclusions (Type II) (vapour + liquid + solid) contain a fluid bubble (20-30 vol.%), an aqueous phase (10-15 vol.%) and several solid phases. Silicate-melt inclusions (Type III) comprise vapour bubbles, silicate
  38. glass and solid phases. Proton-induced X-ray emission (PIXE) analysis revealed high concentrations of
  39. K (~4 wt.%) as well as Ca (~0.5 wt.%), Ti (~1 wt.%), Fe (~2 wt.%), Mn (~0.1 wt.%), V (<0.03 wt.%), Rb (~70 ppm) and Zr (~200 ppm) in the silicate glass. The Ga2O3 abundances and Cr2O3/Ga2O3 values (<1) of the sapphires favour their formation by magmatic processes. The presence of CO2-rich fluids and high K concentrations in the silicate melt inclusions link the origin of the Denchai gem sapphires
  40. to CO2-rich alkaline magmatism." name="eprints.abstract" />
  41. <meta content="2001-12" name="eprints.date" />
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  43. <meta content="Mineralogical Magazine" name="eprints.publication" />
  44. <meta content="65" name="eprints.volume" />
  45. <meta content="6" name="eprints.number" />
  46. <meta content="725-735" name="eprints.pagerange" />
  47. <meta content="10.1180/0026461016560004" name="eprints.id_number" />
  48. <meta content="TRUE" name="eprints.refereed" />
  49. <meta content="0026-461X" name="eprints.issn" />
  50. <meta content="http://dx.doi.org/10.1180/0026461016560004" name="eprints.official_url" />
  51. <meta content="Aspen, P., Upton, B.G.J. and Dicken, A.P. (1990)
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  56. Barr, S.M. and MacDonald, A.S. (1978) Geochemistry
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  59. Barr,S.M. and MacDonald,A.S.(1979)
  60. Palaeomagnetism, age and geochemistry of the
  61. Denchai basalt, Northern Thailand. Earth Planet.
  62. Sci. Lett., 46, 113-24.
  63. Barr, S.M. and MacDonald, A.S. (1981) Geochemistry
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  96. relationships on the join anorthite-forsterite-quartz at
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  100. Oakes, G.M., Barron, L.M. and Lishmond, S.R. (1996)
  101. Alkali basalts and associated volcaniclastic rocks as
  102. a source of sapphire in eastern Australia. Austral. J.
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  105. Griffin, W.L. (1998) Corsilzirspite, a corundumsillimanite-
  106. zircon-hercynite rock: New eveidence on
  107. the origin of Kanchanaburi sapphire, Thailand.
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  110. Asia, Kuala Lumpur, Malaysia, pp. 95-6.
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  144. basalt and alluvium, eastern Thailand: constraints
  145. on the origin of Thai rubies. Mineral. Mag., 65,
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  149. on trace element geochemistry of corundums from
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  153. 99-101.
  154. Upton, B.G.J., Hinton, R.W., Aspen, P., Finch, A. and
  155. Valley, J.W. (1999) Megacrysts and associated
  156. xenoliths: Evidence for migration of geochemically
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  167. (1978) The distribution and some characteristics of
  168. corundum-bearing basalts in Thailand. Journal of
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  170. GEOSEA, 3, M4 1-38." name="eprints.referencetext" />
  171. <meta content="Limtrakun, P. and Zaw, K. and Ryan, C.G. and Mernagh, T.P. (2001) Formation of the Denchai gem sapphires, northern Thailand: evidence from mineral chemistry and fluid/melt inclusion characteristics. Mineralogical Magazine, 65 (6). pp. 725-735. ISSN 0026-461X" name="eprints.citation" />
  172. <meta content="http://eprints.utas.edu.au/2085/1/Limtrakun.Zaw.Ryan.Mernagh.MM.2001.pdf" name="eprints.document_url" />
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  174. <meta content="Formation of the Denchai gem sapphires, northern Thailand: evidence from mineral chemistry and fluid/melt inclusion characteristics" name="DC.title" />
  175. <meta content="Limtrakun, P." name="DC.creator" />
  176. <meta content="Zaw, K." name="DC.creator" />
  177. <meta content="Ryan, C.G." name="DC.creator" />
  178. <meta content="Mernagh, T.P." name="DC.creator" />
  179. <meta content="260100 Geology" name="DC.subject" />
  180. <meta content="The Denchai gem sapphire deposits in Phrae Province, northern Thailand are closely associated with
  181. late Cenozoic alkaline basaltic rocks. The sapphires occur in alluvial placer deposits in palaeo-channels
  182. at shallow depths. Electron microprobe analysis of minor and trace element contents (Fe, Ti, Cr, Ga
  183. and V) of the sapphires indicate the following oxide abundances: Fe2O3 (0.32-1.98 wt.%), TiO2
  184. (0.01-0.23 wt.%), Cr2O3 (<0.01 wt.%), Ga2O3 (0.01-0.03 wt.%) and V2O5 (<0.03 wt.%). Optical
  185. studies of sapphires revealed three types of primary fluid/melt inclusions. CO2-rich inclusions (Type I)
  186. contain three phases (LH2O + LCO2 + V) with the vapour phase comprising <10-15 vol.%. The presence of CO2 was confirmed by microthermometry and laser Raman analysis. Polyphase inclusions (Type II) (vapour + liquid + solid) contain a fluid bubble (20-30 vol.%), an aqueous phase (10-15 vol.%) and several solid phases. Silicate-melt inclusions (Type III) comprise vapour bubbles, silicate
  187. glass and solid phases. Proton-induced X-ray emission (PIXE) analysis revealed high concentrations of
  188. K (~4 wt.%) as well as Ca (~0.5 wt.%), Ti (~1 wt.%), Fe (~2 wt.%), Mn (~0.1 wt.%), V (<0.03 wt.%), Rb (~70 ppm) and Zr (~200 ppm) in the silicate glass. The Ga2O3 abundances and Cr2O3/Ga2O3 values (<1) of the sapphires favour their formation by magmatic processes. The presence of CO2-rich fluids and high K concentrations in the silicate melt inclusions link the origin of the Denchai gem sapphires
  189. to CO2-rich alkaline magmatism." name="DC.description" />
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  196. <meta content="Limtrakun, P. and Zaw, K. and Ryan, C.G. and Mernagh, T.P. (2001) Formation of the Denchai gem sapphires, northern Thailand: evidence from mineral chemistry and fluid/melt inclusion characteristics. Mineralogical Magazine, 65 (6). pp. 725-735. ISSN 0026-461X" name="DC.identifier" />
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  301. <h1 class="ep_tm_pagetitle">Formation of the Denchai gem sapphires, northern Thailand: evidence from mineral chemistry and fluid/melt inclusion characteristics</h1>
  302. <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Limtrakun, P.</span> and <span class="person_name">Zaw, K.</span> and <span class="person_name">Ryan, C.G.</span> and <span class="person_name">Mernagh, T.P.</span> (2001) <xhtml:em>Formation of the Denchai gem sapphires, northern Thailand: evidence from mineral chemistry and fluid/melt inclusion characteristics.</xhtml:em> Mineralogical Magazine, 65 (6). pp. 725-735. ISSN 0026-461X</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2085/1/Limtrakun.Zaw.Ryan.Mernagh.MM.2001.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2085/1/Limtrakun.Zaw.Ryan.Mernagh.MM.2001.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />1048Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="2620" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1180/0026461016560004">http://dx.doi.org/10.1180/0026461016560004</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The Denchai gem sapphire deposits in Phrae Province, northern Thailand are closely associated with&#13;
  303. late Cenozoic alkaline basaltic rocks. The sapphires occur in alluvial placer deposits in palaeo-channels&#13;
  304. at shallow depths. Electron microprobe analysis of minor and trace element contents (Fe, Ti, Cr, Ga&#13;
  305. and V) of the sapphires indicate the following oxide abundances: Fe2O3 (0.32-1.98 wt.%), TiO2&#13;
  306. (0.01-0.23 wt.%), Cr2O3 (&lt;0.01 wt.%), Ga2O3 (0.01-0.03 wt.%) and V2O5 (&lt;0.03 wt.%). Optical&#13;
  307. studies of sapphires revealed three types of primary fluid/melt inclusions. CO2-rich inclusions (Type I)&#13;
  308. contain three phases (LH2O + LCO2 + V) with the vapour phase comprising &lt;10-15 vol.%. The presence of CO2 was confirmed by microthermometry and laser Raman analysis. Polyphase inclusions (Type II) (vapour + liquid + solid) contain a fluid bubble (20-30 vol.%), an aqueous phase (10-15 vol.%) and several solid phases. Silicate-melt inclusions (Type III) comprise vapour bubbles, silicate&#13;
  309. glass and solid phases. Proton-induced X-ray emission (PIXE) analysis revealed high concentrations of&#13;
  310. K (~4 wt.%) as well as Ca (~0.5 wt.%), Ti (~1 wt.%), Fe (~2 wt.%), Mn (~0.1 wt.%), V (&lt;0.03 wt.%), Rb (~70 ppm) and Zr (~200 ppm) in the silicate glass. The Ga2O3 abundances and Cr2O3/Ga2O3 values (&lt;1) of the sapphires favour their formation by magmatic processes. The presence of CO2-rich fluids and high K concentrations in the silicate melt inclusions link the origin of the Denchai gem sapphires&#13;
  311. to CO2-rich alkaline magmatism.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">Definitive version is available online at http://www.minersoc.org/pages/e_journals/minmag.html</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">sapphire, Fluid and melt inclusions, alkaline magmatism, basalt, Thailand.</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/260100.html">260000 Earth Sciences &gt; 260100 Geology</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2085</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Mrs Katrina Keep</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">11 Oct 2007 12:21</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">09 Jan 2008 02:30</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2085;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=2085">item control page</a></p>
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